7371-1MMX50M

Technical Data November 2013 3M™ Anisotropic Conductive Film 7371 Product Description 3M™ Anisotropic Conductive Film (ACF) 7371 is a heatbondable, electrically conductive adhesive film. The unbonded film is slightly tacky at room temperature and consists of a thermoset-elastomer and thermoplastic adhesive matrix randomly loaded with conductive particles. These particles allow interconnection of circuit lines through the adhesive thickness, but are spaced far enough apart for the product to be electrically insulating in the plane of the adhesive. Application of heat and pressure causes the adhesive to flow and to bring the circuit pads into contact by trapping the conductive particles. The adhesive rapidly cross-links at modest bonding temperature and pressure. 3M ACF 7371 may be used to bond a flexible printed circuit to another flexible printed circuit or to a plastic touch screen or plastic flat panel display device. Typical Physical Properties and Performance Characteristics Note: The following technical information and data should be considered representative or typical only and should not be used for specification purposes. Design Requirements Property Value Units Minimum Space Between Conductors 100 (4) micron (mil) Minimum Pitch 200 (8) micron (mil) Minimum Pad Area 0.1 (160) sq. mm (sq. mil) Ambient Physical Properties Property(1) Construction General Properties Property Value Adhesive Type Thermosetting Type Particle Type Gold-Coated Polymer Particle Size 10 micron Liner Type Polyester Film with Silicone Release (1) Adhesive Thickness 25 micron (2) Liner Thickness 50 micron (3) (4) (5) (6) (7) Test Substrates Value Test Method Interconnect Resistance Flex-toPC board(2) < 20 mOhms 3M TM-2314(3) Interconnect Resistance Flex-toAg-Ink/PET(4) < 20 mOhms 3M TM-2314(3) Peel Strength Flex-toITO/PET(5) > 700 gf/cm 3M TM-2313(6) Peel Strength Flex-toAg-Ink/PET(4) > 600 gf/cm 3M TM-2313(6) Peel Strength Flex-tobare-PET(7) > 900 gf/cm 3M TM-2313(6) For a given application, values may differ depending on particular substrate material or type of circuitry. Measured for gold/nickel/copper polyimide flex circuits bonded to printed circuit board. Contact overlap area was 0.38 sq. mm. Pad pitch was 500 microns. 3M internal test method TM-2314 based on IPC 650 - Section 2.6.24. The flex has the shorting strap located near the bond-line to approximate a 4-wire test structure and eliminate most extraneous resistance in the measurement due to the circuit lines. Measured for gold/nickel/copper polyimide flex circuits bonded to silverink/indium-tin-oxide/polyester. Contact overlap area was 2.0 sq. mm. Pad pitch was 2 mm. Measured for gold/nickel/copper polyimide flex circuits bonded to indiumtin-oxide/polyester. Flex circuit pitch was 500 microns. 3M internal test method TM-2313 based on IPC 650 - Section 2.4.9.1. Measured for gold/nickel/copper polyimide flex circuits bonded to bare polyester. Flex circuit pitch was 2 mm. 3M™ Anisotropic Conductive Film 7371 Reliability Performance – Peel Strength(11) Typical Physical Properties and Performance Characteristics (continued) Test Conditions Note: The following technical information and data should be considered representative or typical only and should not be used for specification purposes. Ambient Physical Properties – Peel Strength(8) Peel Strength (gf/cm) 3M TM-2313(12) 100°C x 1000 hrs > 500 -40°C to 85°C x 1000 cycles > 500 85°C / 85% r. h. x 1000 hrs > 500 Boxplot of Peak Peel Strength vs. Bonding Temperature 1400 Peak Peel Strength (gf/cm) 1200 PI Flex - to - Glass All Bonds 15sec and 3MPa Initial Peel Values Assembly Process Techniques Assembly Process 1000 A source of heat and pressure, such as a thermo-compression (hot bar) bonder is required for use of 3M™ Anisotropic Conductive Film 7371. Several commercially available models exist; a list of vendors can be obtained by calling the toll free number on the back of this Technical Data Sheet. 800 600 400 200 0 147 160 180 190 Temperature (oC) 200 210 Bonding of 3M ACF 7371 requires a three-part procedure: Tacking the film to one substrate (pre-tacking) Reliability Performance – Electrical Contact Test Conditions (9) Removing the release liner Bonding the first substrate to the second substrate. Interconnect Resistance (mOhms) 3M TM-2314(10) 100°C x 1000 hrs < 100 -40° to 85°C x 1000 cycles < 100 85°C / 85% r. h. x 1000 hrs < 100 A pre-tacking temperature of 90°C under a pressure of about 10 kg/cm2 should be used (see Table below). For automated ACF application: Set the ACF pretacking equipment to deliver the conditions provided in the Tacking and Bonding Conditions Table below. Slight adjustment to these conditions may be necessary for each application or for different types of circuitry. For manual ACF application: Cut the adhesive to the size of the flex circuit. Place the adhesive on the flex and set flex on hot plate at setpoint up to 90°C. Use roller to press adhesive onto the flex. After allowing flex and adhesive to cool, remove liner. (8) Measured for gold/nickel/copper polyimide flex circuits bonded to glass. Pad pitch was 100 microns. (11) Measured for gold/nickel/copper polyimide flex circuits bonded to Ag-Ink/ ITO/polyester. Contact overlap area was 2.0 sq. mm. Pad pitch was 2 mm. (9) Measured for gold/nickel/copper polyimide flex circuits bonded to Ag-Ink/ indium-tin-oxide/polyester. Contact overlap area was 2.0 sq. mm. Pad pitch was 2 mm. Also, measured for gold/nickel/copper polyimide flex circuits bonded to printed circuit board. Overlap area was 0.38 sq. mm. Pad pitch was 500 microns. (12) 3M internal test method TM-2313 based on test method IPC 650 - Section 2.4.9.1. (10) 3M internal test method TM-2314 based on IPC 650 - Section 2.6.24. The flex has the shorting strap located near the bond-line to approximate a 4-wire test structure and eliminate most extraneous resistance in the measurement due to the circuit lines. (2) 3M™ Anisotropic Conductive Film 7371 Assembly Process Techniques (continued) 200 Tacking and Bonding Conditions 180 Conditions Tacking Conditions Temperature(13) Pressure Time 60 - 90°C 1 - 15 kg/cm2 ~1 sec Bonding Conditions Temperature(13) Pressure Time(14) 140 to 170°C 10 - 20 kg/cm2 10 - 20 sec 160 Temperature (oC) Procedure 140 120 Thermode Released 100 80 170oC x 15 sec 60 140oC x 10 sec 40 20 0 0 Final bonding must be done under heat and pressure, with a typical desirable bond line temperature that reaches at least 140°C after 10 seconds at a pressure of at least 10kg/cm2 (see Table above). This has been (14) The required minimum bonding temperature is usually reached at the endpoint of bonding time. The optimum bonding temperature and time may be different depending on customer application and design. Also, it may be desirable to hold pressure while cooling to below 100ºC for maximum performance. (15) Bonding temperature up to 190°C has been shown to be acceptable for 3M™ Anisotropic Conductive Film 7371. 10 12 14 16 Figure 1. Graph of ACF temperature vs. time profile showing typical examples of bonding cycle. Predicted 3M™ ACF 7371 Cross-link Reaction 140.0°C 150.0°C 160.0°C 170.0°C 180.0°C 190.0°C 100% 90% Conversion (%) 80% shown in Figure 1. Electrical contact between the circuits is typically achieved shortly after the thermode is pressed against the parts. Additional time at temperature is necessary to cross-link the thermoset-elastomer material to generate peel strength and the ultimate reliability. Bond times may vary depending upon the substrates to be bonded. (Optionally, for maximum mechanical and electrical performance, the pressure may be maintained while cooling to below 100ºC. This increases the total bond time. The time required to drop adhesive bond-line temperature below 100ºC is highly dependent on the bonding equipment used.) Temperature measured in the adhesive. Thermode set points will be higher and will depend upon the substrate materials and bonding equipment. A typical set-up for tacking is a setpoint temperature of 125ºC. Typical set-up for a flex circuit to polyester touch screen bond is a thermode temperature of 250ºC and bonding time of at least 10 seconds (see next note). 8 6 Time (sec) achieved using a total bond time of 10-20 seconds where over the first 3-5 seconds the adhesive ramps quickly to near the target temperature and over the last 5-17 seconds the temperature reaches between 140°C and 170°C.(15) A plot of the temperature vs. time profile is (13) 4 2 70% 60% 50% 40% 30% 20% 10% 0% 0 10 20 30 40 50 60 Time (sec) Figure 2. Graph of predicted cross-link reaction compared with bonding temperature and time. A comparison of the predicted level of cross-link reaction across a range of bonding temperature and bonding time is shown in Figure 2. Repair Bonds made with 3M™ Anisotropic Conductive Film 7371 may be repairable. The method for successful rework can show considerable variation for different design applications, process parameters, and equipment capabilities. Contact your local Tech Service Representative for further information. (3) 3M™ Anisotropic Conductive Film 7371 Assembly Process Techniques (continued) Storage The 3M™ Anisotropic Conductive Film 7371 should be kept frozen in the original airtight shipping bag and stored at temperatures ≤ 2°C. The product should be allowed to warm to room temperature for approximately 30 minutes prior to use to prevent moisture condensation on the film. Whenever possible, 3M ACF 7371 should be kept away from high humidity environments as absorbed water can lead to moisture volatilization producing bubbles during heat bonding or gradual degradation of the product. The 3M ACF 7371 can be held at room temperature for product utilization provided the cumulative room temperature shelf life of 4 weeks is not exceeded. Shelf Life Data Storage Environment Value Freezer (< 2°C) 12 months Room Temperature 4 weeks Product Selection Guide Flex Type Silver Ink on Polyester Gold/Copper on Polyester Connection Type Gold/Copper on Polyimide ACF 5363 1 2 Flex to Glass Flex to Plastic Device X Pitch and Space Requirements Flex to PCB Flex to Flex Minimum Space Between Conductors X X 100 micron 0.15 sq. mm X X 250 micron 0.75 sq. mm Minimum Pad Area ACF 7303 X X X X1 X2 ACF 7371 X X X X X X 100 micron 0.10 sq. mm ACF 7371-20 X X X X X X 100 micron 0.50 sq. mm ACF 7376-10 X X X X X X X 70 micron 0.10 sq. mm ACF 7376-30 X X X X X X X 100 micron 0.50 sq. mm ACF 7379 X X X X 50 micron 0.05 sq. mm Tested only for silver frit; not suitable for ITO traces. Suitable for silver ink traces only; not suitable for ITO traces. (4) 3M™ Anisotropic Conductive Film 7371 Technical Information Warranty, Limited Remedy, and Disclaimer The technical information, recommendations and other statements contained in this document are based upon tests or experience that 3M believes are reliable, but the accuracy or completeness of such information is not guaranteed. Unless an additional warranty is specifically stated on the applicable 3M product packaging or product literature, 3M warrants that each 3M product meets the applicable 3M product specification at the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M product does not conform to this warranty, then the sole and exclusive remedy is, at 3M’s option, replacement of the 3M product or refund of the purchase price. Product Use Many factors beyond 3M’s control and uniquely within user’s knowledge and control can affect the use and performance of a 3M product in a particular application. Given the variety of factors that can affect the use and performance of a 3M product, user is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user’s method of application. Limitation of Liability Except where prohibited by law, 3M will not be liable for any loss or damage arising from the 3M product, whether direct, indirect, special, incidental or consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability. Electronics Markets Materials Division 3M Center, Building 225-3S-06 St. Paul, MN 55144-1000 1-800-251-8634 phone 651-778-4244 fax www.3M.com/electronics 3M is a trademark of 3M Company. Please recycle. Printed in U.S.A. © 3M 2013. All rights reserved. 60-5002-0443-7 (5)