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SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Lötzinn ECOLOY® TSC Synonyms Lötzinn ECOLOY® TSC (Sn, Cu 0,5-0,9%, Ag 3,6-4,0%) * Lötzinn ECOLOY® TSC 263 (Sn, Cu 0,2-0,4%, Ag 2,4-2,8%) * Lötzinn ECOLOY® TSC 283 (Sn, Cu 0,2-0,4%, Ag 2,6-3,0%) * Lötzinn ECOLOY® TSC 305 (Sn, Cu 0,3-0,7%, Ag 2,8-3,2%) * Lötzinn ECOLOY® TSC 0307 (Sn, Cu 0,5-0,9%, Ag 0,2-0,4%) * Lötzinn ECOLOY® TSC 0307 (Sn, Cu 0,6-0,8%, Ag 0,25-0,35%) * Lötzinn ECOLOY® TSC 355 (Sn, Cu 0,4-0,6%, Ag 3,3-3,7%) * Lötzinn ECOLOY® TSC 385 (Sn, Cu 0,4-0,6%, Ag 3,6-4,0%) * Lötzinn ECOLOY® TSC 409 (Sn, Cu 0,8-1,0%, Ag 3,8-4,2%) Issue date 20-August-2012 Version number 1.3 Revision date 01-October-2013 Supersedes date 10-April-2013 Product use professional use 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Metal alloy for soft solder Uses advised against None known 1.3. Details of the supplier of the safety data sheet Company name Address Contact person Telephone number Fax e-mail Contact person Emergency telephone number STANNOL GmbH Oskarstr. 3-7 42283 Wuppertal Germany Dr. Sven Mönninghoff +49 (0) 202 585-129 +49 (0) 202 585 155 sven.moenninghoff@stannol.de HSE-BBS@bayer.com +49 (0) 202 585 129 (8:00 a.m. – 4:00 p.m. (MET)) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This preparation does not meet the criteria for classification according to Directive 1999/45/EC as amended. Hazard summary Physical hazards Not classified for physical hazards. Health hazards Not classified for health hazards. However, occupational exposure to the mixture or substance(s) may cause adverse health effects. Environmental hazards Not classified for hazards to the environment. Specific hazards Not available. Main symptoms Not available. 2.2. Label elements Label according to Directive 67/548/EEC or 1999/45/EC as amended EC number - EC label Not available. R-phrases Not available. S-phrases Not available. Authorisation number Not available. Supplemental label information Not applicable. 2.3. Other hazards Not assigned. Material name: Lötzinn ECOLOY® TSC 7218 Version No.: 1.3 Revision date: 01-October-2013 SDS UK Issue date: 20-August-2012 1/7 SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Chemical name % Tin Classification: Notes 1mm) TWA 0.1 mg/m3 (7440-22-4) Tin (7440-31-5) TWA 2 mg/m3 Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoring procedures Follow standard monitoring procedures. 8.2. Exposure controls Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide adequate general and local exhaust ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Chemical goggles are recommended. Skin protection - Hand protection Wear protective gloves. Leather gloves. - Other Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Normal work clothing (long sleeved shirts and long pants) is recommended. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Thermal hazards Thermally protective gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves. Avoid contact with molten material. Hygiene measures Avoid contact with skin. When using, do not eat, drink or smoke. Handle in accordance with good industrial hygiene and safety practices. Avoid contact with eyes. Environmental exposure controls Not available. Material name: Lötzinn ECOLOY® TSC 7218 Version No.: 1.3 Revision date: 01-October-2013 SDS UK Issue date: 20-August-2012 3/7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Solid. Form barren, Roll. Colour Metallic. Odour Odourless. Odour threshold Not available. pH Not applicable. Melting point/freezing point 217 °C (422.6 °F) Initial boiling point and boiling range Not available. Flash point Not applicable. Evaporation rate Not applicable. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Vapour pressure Not applicable. Vapour density Not applicable. Relative density Not available. Solubility(ies) insoluble Partition coefficient (n-octanol/water) Not available. Decomposition temperature Not available. Viscosity Not applicable. Explosive properties Not available. Oxidizing properties Not available. 9.2. Other information Density 7.00 - 9.00 g/ml @ 20 °C SECTION 10: Stability and reactivity 10.1. Reactivity Strong oxidizing agents. 10.2. Chemical stability Material is stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid None under normal conditions. 10.5. Incompatible materials Acids. Chlorine. 10.6. Hazardous decomposition products Not available. SECTION 11: Toxicological information General information Not available. Information on likely routes of exposure Ingestion Not available. Inhalation Not available. Skin contact Not available. Eye contact Not available. Symptoms Not available. 11.1. Information on toxicological effects Material name: Lötzinn ECOLOY® TSC 7218 Version No.: 1.3 Revision date: 01-October-2013 SDS UK Issue date: 20-August-2012 4/7 Components Species Test results Acute Dermal LD50 Rat > 2000 mg/kg, OECD Guideline 402 Oral LD50 Rat > 2500 mg/kg, OECD Guideline 401 Acute Dermal LD50 Rat > 2000 mg/kg Oral LD50 Rat > 5000 mg/kg Copper Metal (7440-50-8) Silver (metal, >1mm) (7440-22-4) Skin corrosion/irritation Not available. Serious eye damage/irritation Not available. Respiratory sensitisation Not available. Skin sensitisation Not available. Germ cell mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity single exposure Not available. Specific target organ toxicity repeated exposure Not available. Aspiration hazard Not available. Mixture versus substance information Not available. Other information Not available. SECTION 12: Ecological information 12.1. Toxicity Not expected to be harmful to aquatic organisms. Avoid discharge into drains, water courses or onto the ground. 12.2. Persistence and degradability No data is available on the degradability of this product. 12.3. Bioaccumulative potential Not available. Partition coefficient n-octanol/water (log Kow) Not available. Bioconcentration factor (BCF) Not available. 12.4. Mobility in soil Not available. 12.5. Results of PBT and vPvB assessment Not a PBT or vPvB substance or mixture. 12.6. Other adverse effects Not available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Residual waste Dispose of in accordance with local regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. EU waste code The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal methods/information Collect and reclaim or dispose in sealed containers at licensed waste disposal site. SECTION 14: Transport information ADR Not regulated as dangerous goods. IATA Not regulated as dangerous goods. Material name: Lötzinn ECOLOY® TSC 7218 Version No.: 1.3 Revision date: 01-October-2013 SDS UK Issue date: 20-August-2012 5/7 IMDG Not regulated as dangerous goods. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Not listed. Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I as amended Not listed. Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Not listed. Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Not listed. Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Not listed. Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Not listed. Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Not listed. Authorisations Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorisation Not listed. Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Not regulated. Other EU regulations Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances Not regulated. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Not regulated. Directive 94/33/EC on the protection of young people at work Not regulated. Other regulations The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. The product does not need to be labelled in accordance with EC directives or respective national laws. National regulations Not available. 15.2. Chemical safety assessment No Chemical Safety Assessment has been carried out. SECTION 16: Other information List of abbreviations Not available. References Not available. Information on evaluation method leading to the classification of mixture Not available. Material name: Lötzinn ECOLOY® TSC 7218 Version No.: 1.3 Revision date: 01-October-2013 SDS UK Issue date: 20-August-2012 6/7 Full text of any statements or R-phrases and H-statements under Sections 2 to 15 None. Training information Not available. Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. SDS sections updated Product and company identification: Synonyms Material name: Lötzinn ECOLOY® TSC 7218 Version No.: 1.3 Revision date: 01-October-2013 SDS UK Issue date: 20-August-2012 7/7