19-348

1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com BLACK SWAN MFG. CO. BLACK SWAN MFG. CO. MSDS Number: 124 Revision Date: 01/20/2015 Supersedes Date: 01/23/2012 GHS SAFETY DATA SHEET GHS SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET SECTION 1 - IDENTIFICATION Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 SECTION 1 - IDENTIFICATION Manufacturer: For any Transportation or Medical Chemical Emergencies call: Manufacturer: Black Swan Mfg. Co. For any Transportation or Medical Chemical Emergencies call: Black Swan Mfg. St. Co. PUTTY Product 4540 Name: EPOXY W. Thomas INFOTRAC 4540 W. Thomas St. INFOTRAC Chicago, IL 60651-3318 Chicago, IL 60651-3318 Tel.: 800-252-5796 (800) 535-5053 OR (352) 323-3500 Tel.: 800-252-5796 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION (800) 535-5053 OR (352) 323-3500 Fax: 773-227-3705 Fax: 773-227-3705 Web Site : www.blackswanmfg.com 24 hours per day - 7 days a week Web Site : www.blackswanmfg.com Product Type: Adhesive Emergency Contact: Chemtrec a week 24 hours per day - 7 days E-mail : info@blackswanmfg.com E-mail : info@blackswanmfg.com Product Name: EPOXY PUTTY Phone: (800) and patching Recommended Use: Plugging, sealing, mending 424-9300 and patching Plugging, sealing, Recommended Part Number(s): 19-348 almost anything,Use: including metals, wood,mending glass, concrete, ceramics Product Name: Stik-It Epoxy Putty almost anything, including metals, wood, glass, concrete, ceramics Product Name: Stik-It Epoxy Putty and most plastics. and most plastics. SECTION 2: HAZARDS IDENTIFICATION SECTION 2 – HAZARD(S) IDENTIFICATION SECTION 2 – HAZARD(S) IDENTIFICATION NFPA GHS Classification Labels Labels None None HEALTH HAZARD AZARD 4 – Deadly HEALTH HAZARD AZARD 3 - Extreme Danger 4 – Deadly 2 – Hazardous 3 - Extreme Danger 1 - Slight Hazardous 2 – Hazardous 0 - Normal Material 1 - Slight Hazardous 0 - Normal Material Signal Word Signal Word None None HMIS HMIS HEALTH HEALTH FLAMMABILITY FLAMMABILITY REACTIVITY REACTIVITY NFPA SPECIFIC HAZARD 2 2 1 1 1 1 1 2 11 2 1 Oxidizer OX SPECIFIC HAZARD Acid ACID Oxidizer OX Alkali ALK Acid ACID Corrosive COR Alkali ALK Use NO WATER W Corrosive COR Radioactive Use NO WATER W Radioactive Hazardous Statements H319: Causes serious eyeHazardous irritation Statements H319: Harmful Causes serious eye irritation H332: if inhaled H332: Harmful if inhaled FIRE HAZARD Flash Points FIRE HAZARD 4 – Below 73°F Flash Points 3 – Below 100°F 4 – Below 73°F 2 – Above 100°F, Not 3 – Below 100°F exceeding 200°F 2 – Above 100°F, Not 1 – Above 200°F exceeding 200°F 0 – Will not burn 1 – Above 200°F 0 – Will not burn REACTIVITY 4 – May detonate REACTIVITY 3 – Shock and heat 4 – May detonate may detonate 3 – Shock and heat 2 – Violent chemical may detonate change 2 – Violent chemical 1 – Unstable change if heated 0 – Stable 1 – Unstable if heated 0 – Stable GHS Classification Environmental Health Environmental HealthEstablished Acute Toxicity:Not AcuteIrritation: Toxicity:Not cute Aquatic Toxicity: Not Established Skin Not Established Acute cute Aquatic SkinIrritation: Irritation: Not Not Established Established Chronic Acute Eye Aquatic Toxicity: Toxicity: Not Not Established Established Eye Irritation: Not Established Chronic Aquatic Toxicity: Not Established Skin Sensitization: NO Skin Sensitization: NO Physical PhysicalNot Established Flammability: Flammability: Not Established Precautionary Statements Precautionary Statements P102: Keep out of reach of children P102: Keep out of reach of children SECTION /3INFORMATION – COMPOSITION / INFORMATION ON INGREDIENTS SECTION 3: COMPOSITION ON INGREDIENTS SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Chemicals EINECS# Approx % CAS# REACH Hazardous Chemicals EINECS# Approx % CAS# REACH Pre-registration Number Pre-registration Number Non-hazardous ingredients N/A N/A N/A 30-60% Non-hazardous ingredients N/A38-6 N/A N/A 30-60% BISPHENOL A DIGLYCIDYL ETHER RESIN 25068-38 N/A N/A 10-30% BISPHENOL ASILICATE DIGLYCIDYL ETHER RESIN 14807-96 25068-38 N/A 9 N/A 10-30% 38-6 MAGNESIUM HYDRATE 238-877-9 96-6 N/A 10-30% 10 MAGNESIUM SILICATE 14807-96 238-877-9 96-6 N/A 10-30% 10 CRYSTALLINE SILICA HYDRATE 14808-60 238-878-4 60-7 49 N/A 0.1-1% 0.1 CRYSTALLINE SILICA 238-878-4 4 N/A by the US EPA, or are0.1-1% 0.1 exempt from that listing. All of the constituents of this adhesive product are14808-60 listed on60-7 the TSCA inventory of chemical substances maintained All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing. SECTION 4 – FIRST-AID MEASURES SECTION 4 – FIRST-AID MEASURES Inhalation: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician. physician Inhalation: Move into fresh clothing air. If notand breathing, give artificial respiration. breathing is difficult, give oxygen and call physician. physician Skin: Remove contaminated shoes. Wash skin thoroughly withIfsoap and water. Skin: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. Eyes: Flush with water for 15 minutes. If irritation persists, get medical attention. Eyes: FlushGive with1water for 15 minutes. irritation persists, get medical attention. Ingestion: or 2 glasses of water. IfDO NOT INDUCE VOMITING. Contact physician im immediately. Part Number(s): Page 1 of 5 Ingestion: Give 1 or19-348 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician im immediately. 2 None SPECIFIC HAZARD HMIS HEALTH 2 FLAMMABILITY 1 REACTIVITY 1 Oxidizer Acid Alkali Corrosive Use NO WATER Radioactive 1 1 – Above 200°F 0 – Will not burn REACTIVITY Eye Irritation: Not Established Chronic Aquatic Toxicity: Not Established Skin Sensitization: NO 4 – May detonate 3 – Shock and heat may detonate 2 – Violent chemical change 1 – Unstable if heated 0 – Stable OX ACID ALK COR W Physical Flammability: Not Established Precautionary Statements Hazardous Statements 1801 Morgan Street MSDS Number: 124 H319: Causes serious eye irritation P102: Keep out of reach of children Rockford, IL 61102 Revision Date: 01/20/2015 H332: Harmful if inhaled Phone: (815) 968-9661 Supersedes Date: 01/23/2012 Fax: (815) 968-9731 SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS www.gcelectronics.com Hazardous Chemicals CAS# EINECS# REACH Approx % Pre-registration Number MATERIAL SAFETY DATA SHEET Non-hazardous ingredients N/A N/A N/A 30-60% Complies with OSHA Hazard CFR 1910.1200 BISPHENOL A DIGLYCIDYL ETHER RESIN 25068-38 N/A Standard 29 N/A 10-30% 38-6Communication MAGNESIUM SILICATE HYDRATE 14807-96 238-877-9 96-6 9 N/A 10-30% 10 CRYSTALLINE SILICA EPOXY PUTTY 14808-60 238-878-4 60-7 4 N/A 0.1-1% 0.1 Product Name: All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing. SECTION 4: FIRST AID MEASURES SECTION 4 – FIRST-AID MEASURES Inhalation: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician. physician Skin: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. Eyes: Flush with water for 15 minutes. If irritation persists, get medical attention. Ingestion: Give 1 or 2 glasses of water. DO NOTGHS INDUCE VOMITING. Contact physician im immediately. SAFETY DATA SHEET GHS SAFETY DATA SHEET GHS SAFETY DATA SHEET SECTION 5: FIRE FIGHTING MEASURES SECTION 5 – FIRE-FIGHTING MEASURES SECTION 5 – FIRE-FIGHTING MEASURES Fire Hazard: None SECTION 5 – FIRE-FIGHTING MEASURES Fire Hazard: None Combustion Products: None Combustion None Dioxide Gas, Dry Chemical Powder Fire Hazard:Products: None Extinguishing Media: Carbon Extinguishing Media: Carbon Dioxide Gas,Foam Dry Chemical Powder Combustion Products: None Unsuitable Extinguishing Media: Water, Unsuitable Extinguishing Media: Water, Foam Extinguishing Media: Carbon Dioxide Gas, Dry Protective Equipment: Self-contained breathingChemical apparatusPowder {(SCBA), MSHA/NIOSH}. Full protective gear. Protective Equipment: Self-contained breathing {(SCBA), MSHA/NIOSH}. Full protective gear. Unsuitable Extinguishing Media: Water, Foam Special Fire Fighting Procedures: Evacuate areaapparatus of unprotected personnel. Use cold water spray to cool fire exposed containers, to Special Fire Fighting Procedures: Evacuate area of unprotected personnel. Use cold water spray to cool firefire exposed Protective Equipment: Self-contained breathing apparatus {(SCBA), MSHA/NIOSH}. Full protective gear. minimize risk of rupture. Do NOT enter confined fire space without full protective gear. If possible, contain run-offcontainers, water. to minimize riskFighting of rupture. Do NOT enter confined space without full protective gear. If possible, run-offcontainers, water. Special Fire Procedures: Evacuate areafire of unprotected personnel. Use cold water spray to contain cool firefire exposed to minimize risk of rupture. Do NOT enter confined fire space withoutPage full protective gear. If possible, contain fire run-off water. 1 of 3 SECTION 6: ACCIDENTAL RELEASE SECTIONMEASURES 6 – ACCIDENTAL RELEASE MEASURES SECTION 6 – ACCIDENTAL` RELEASE MEASURES Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. SECTION 6 – ACCIDENTAL RELEASE MEASURES Personal Precautions: Protective Equipment:Evacuate None area and keep unnecessary and unprotected personnel from entering the spill area. Protective Equipment: None Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Emergency Procedures: None Emergency Procedures: None Protective Equipment: None Environmental Precautions: Avoid runoff into storm sewers, ditches and waterways. Environmental Precautions: Avoid spill runoff intoinert storm sewers,then ditches Emergency Procedures: None Methods for Cleaning Up: Absorb with material, placeand in awaterways. chemical waste container. Provide ventilation. Clean up spills Methods for Cleaning Up: Absorb spill with inert material, then place in awaterways. chemical waste ventilation. up spills Environmental Precautions: Avoid runoff into storm sewers, ditches and immediately observing precautions in the protective equipment section. After removal, flushcontainer. spill areaProvide with soap and waterClean to remove trace with soap and water to remove trace immediately observing precautions in the protective equipment section. After removal, flush spill area Methods for Cleaning Up: Absorb spill with inert material, then place in a chemical waste container. Provide ventilation. Clean up spills residue. Avoid personal contact and breathing vapors or mists. Ventilate area. residue. Avoid personalprecautions contact andinbreathing vaporsequipment or mists. Ventilate area. removal, flush spill area with soap and water to remove trace immediately observing the protective section. After residue. Avoid personal contact and breathing vapors or mists. Ventilate area. SECTION 7 – HANDLING AND STORAGE SECTION 7 – HANDLING AND STORAGE SECTION 7: HANDLING AND STORAGE Handling SECTION 7 – HANDLING AND STORAGE Storage Handling Storage Use with adequate ventilation. Avoid breathing vapors, aerosol or Store in a cool, dry, well-ventilated area away from sources of heat Use with adequate ventilation. Avoid breathing vapors, aerosol or Store in a cool, dry, well-ventilated area awaytightly from closed sourceswhen of heat Handling Storage mist. Provide appropriate ventilation/respiratory protection against and incompatible materials. Keep container not mist. Provide appropriate ventilation/respiratory protection against and incompatible materials. Keep container tightly closed when not Use with adequate ventilation. Avoid breathing vapors, aerosol or Store in a cool, dry, well-ventilated area away from sources of heat decomposition products during welding/flame cutting operations in use. decomposition productsdust during welding/flame cutting in use. mist. Provide ventilation/respiratory protection against and incompatible materials. Keep container tightly closed when not and to protectappropriate against during sanding /grinding ofoperations cured and to protect against dust during sanding /grinding of cured in use. decomposition products during welding/flame cutting operations product. product. and to protect against dust during sanding /grinding of cured product. SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Hazardous Chemicals ACGIH-TLV ACGIH-STEL OSHA-PEL Hazardous Chemicals ACGIH-TLV ACGIH-STEL OSHA-PEL Exposure Limits Non-hazardous ingredients N/A N/A N/A Non-hazardous ingredientsETHER RESIN ACGIH-TLV N/A N/A N/A Hazardous ACGIH-STEL OSHA-PEL BISPHENOLChemicals A DIGLYCIDYL N/A N/A N/A BISPHENOL A SILICATE DIGLYCIDYL ETHER RESIN Non-hazardous ingredients N/A MAGNESIUM HYDRATE 2N/A mg/m3 N/A 20N/A mppcf Part Number(s): 19-348 Page 2 of 5 MAGNESIUM SILICATE HYDRATE 2 mg/m3 N/A 20 mppcf BISPHENOL A DIGLYCIDYL ETHER RESIN N/A N/A CRYSTALLINE SILICA 0.025 mg/m3 N/A 10N/A mg/m3 CRYSTALLINE SILICA HYDRATE 0.025 mg/m3 N/A 10 MAGNESIUM SILICATE 2 mg/m3 N/A 20 mg/m3 mppcf Engineering Controls: Use appropriate engineering controls such as process enclosures, local exhaust ventilation, or other engineering CRYSTALLINE SILICA 0.025 mg/m3 N/A 10 mg/m3 Engineering Controls: Use levels appropriate controls suchlimits. as process enclosures, local exhaust ventilation, or other engineering controls to control airborne belowengineering recommended exposure controls to control airborne levels below recommended exposure limits.  Unsuitable Extinguishing Media: Water, Foam apparatus {(SCBA), MSHA/NIOSH}. Full protective gear. Protective Equipment: Self-contained breathing Protective Self-contained breathing {(SCBA), MSHA/NIOSH}. Fullspray protective gear. Special FireEquipment: Fighting Procedures: Evacuate areaapparatus of unprotected personnel. Use cold water to cool fire exposed containers, to Special Fire Fighting Procedures: Evacuate area of unprotected personnel. Use cold water spray to cool firefire exposed to minimize risk of rupture. Do NOT enter confined fire space without full protective gear. If possible, contain run-offcontainers, water. minimize risk of rupture. Do NOT enter confined fire space without full protective gear. If possible, contain fire run-off water. SECTION 6 – ACCIDENTAL RELEASE MEASURES SECTION 6 – ACCIDENTAL RELEASE MEASURES Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Personal Precautions: Protective Equipment:Evacuate None area and keep unnecessary and unprotected personnel from entering the spill area. Protective EmergencyEquipment: Procedures:None None 1801 Morgan StreetNoneAvoid runoff into storm sewers, ditches and waterways. MSDS Number: 124 Emergency Procedures: Environmental Precautions: Environmental Precautions: Avoidspill runoff into storm sewers, ditches Rockford, 61102 Revision Date: 01/20/2015 Methods for IL Cleaning Up: Absorb with inert material, then placeand in awaterways. chemical waste container. Provide ventilation. Clean up spills Methods for Cleaning Up: Absorbinspill inert material, then place in a chemical Provide ventilation. Clean up spills immediately observing precautions the with protective equipment section. After removal,waste flushcontainer. spill area with soap and water to remove trace Phone: (815) 968-9661 Supersedes Date: 01/23/2012 immediately observing the protective section. After residue. Avoid personalprecautions contact andinbreathing vaporsequipment or mists. Ventilate area. removal, flush spill area with soap and water to remove trace Fax: (815) 968-9731 residue. Avoid personal contact and breathing vapors or mists. Ventilate area. www.gcelectronics.com SECTION 7 – HANDLING AND STORAGE SECTION 7SAFETY – HANDLING AND SHEET STORAGE Storage Handling MATERIAL DATA Handling Storage Use with adequate ventilation. Avoid breathing vapors, aerosol or Store in a cool, dry,29 well-ventilated area away from sources of heat Complies with OSHA Hazard Communication Standard CFR 1910.1200 Use adequate ventilation. Avoid breathing vapors, aerosol or mist.with Provide appropriate ventilation/respiratory protection against mist. Provide appropriate ventilation/respiratory protection against decomposition products during welding/flame cutting operations decomposition products during welding/flame cutting and to protect Name: against dust during sanding /grinding ofoperations cured Product EPOXY PUTTY and to protect against dust during sanding /grinding of cured product. product. Store in a cool, dry, well-ventilated area away fromclosed sources of heat and incompatible materials. Keep container tightly when not and incompatible materials. Keep container tightly closed when not in use. in use. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTON SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Exposure Limits ACGIH-TLV ACGIH-STEL OSHA-PEL Hazardous Chemicals Hazardous Chemicals ACGIH-TLV ACGIH-STEL OSHA-PEL Non-hazardous ingredients N/A N/A N/A Non-hazardous ingredients BISPHENOL A DIGLYCIDYL ETHER RESIN N/A N/A N/A BISPHENOL DIGLYCIDYL ETHER RESIN N/A N/A MAGNESIUMASILICATE HYDRATE 2 mg/m3 20N/A mppcf MAGNESIUM SILICATE 2 mg/m3 20mg/m3 mppcf CRYSTALLINE SILICA HYDRATE 0.025 mg/m3 N/A 10 CRYSTALLINE SILICA 0.025 mg/m3 N/A 10 mg/m3 Engineering Controls: Use appropriate engineering controls such as process enclosures, local exhaust ventilation, or other engineering Engineering Controls: Uselevels appropriate controls suchlimits. as process enclosures, local exhaust ventilation, or other engineering controls to control airborne below engineering recommended exposure controls to control levels below recommended exposure limits. Ventilation: Good airborne general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable Ventilation: Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment. personal Personalprotective Protectiveequipment. Equipment – Respiratory: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister Personal Protectiveunder Equipment – Respiratory:where A NIOSH approved air-purifying respiratortowith an organic vapor cartridge or canister limits. Protection provided may be permissible certain circumstances airborne concentrations are expected exceed exposure may permissible under certain circumstances where airborne are expected exceed exposure limits. Protection provided by airbepurifying respirators is limited. Use a positive pressure airconcentrations supplied respirator if there istoany potential for an uncontrolled release, by air purifying respirators is limited. pressure air supplied respirator if there is any for an uncontrolled exposure levels are not known, or any Use othera positive circumstances where air purifying respirators may not potential provide adequate protection. release, exposure are not known, or –any other circumstances air purifying respirators may not apparel provideto adequate Personal levels Protective Equipment Skin: Wear appropriatewhere protective gloves and other protective prevent protection. skin contact. Personal Protective Equipment – Skin: other protective Eyes: Wear appropriate protective gloves glassesand or splash goggles. apparel to prevent skin contact. Personal Protective Equipment – Eyes: Wear appropriate protective glasses or splash goggles. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Odor: Appearance: pH: Odor: Melting Point: pH: FreezingPoint: Point: Melting Boiling FreezingPoint: Point: Boiling Point: Putty Slight Putty Not Established Slight Not Established Not Not Established Established >500°F (260°C) Not Established >500°F (260°C) SECTIONFlash 9 – Point: PHYSICAL>400°F & CHEMICAL PROPERTIES (205.4°C) Vapor Pressure: Specific Gravity: Flash Point: Solubility (H2O): Specific Gravity: Evaporation Rate Solubility (H2O): Vapor Density: Evaporation Rate VOC: Vapor Density: VOC: 1.19 >400°F (205.4°C) Negligible 1.19