C
R
CR
Primary Battery
Lithium Manganese
Dioxide Battery (Li/MnO2)
LITHIUM MANGANESE DIOXIDE BATTERY
Safety Instructions
This battery contains lithium, organic solvents, and other combustible materials. For this reason, improper handling of the battery could lead to
distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble. Please observe the following instructions to
prevent accidents.
(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Warnings — Handling
Keep battery out of reach of children.
Swallowing can lead to chemical burns, perforation of soft tissue, and
death. Severe burns can occur within 2 hours of ingestion. If swallowed,
seek medical attention immediately.
Never weld the terminals or weld a wire to the body of the
battery directly.
The heat of welding or soldering could cause the lithium to melt, or
cause damage to the insulating material in the battery. This could
cause distortion, leakage, overheating, explosion, or fire. When
soldering the battery directly to equipment, solder only the tabs or
leads. Even then, the temperature of the soldering iron must be
below 350 deg. C and the soldering time less than 5 seconds. Do
not use a soldering bath, because the circuit board with battery
attached could stop moving or the battery could drop into the bath.
Moreover do not use excessive solder, because the solder could
flow to unwanted portions of the board, leading to a short-circuit or
charging of the battery.
Never charge.
The battery is not designed to be charged by any other electrical
source. Charging could generate gas and internal short-circuiting,
leading to distortion, leakage, overheating, explosion, or fire.
Never heat.
Heating the battery to more than 100 deg. C* could increase the internal
pressure, causing distortion, leakage, overheating, explosion, or
fire. (* Consult Maxell regarding heat resistant coin type lithium
manganese dioxide batteries.)
Never use different batteries together.
Using different batteries together, i.e. different type or used and new
or different manufacturer could cause distortion, leakage,
overheating, explosion, or fire because of the differences in battery
property. If using two or more batteries connected in series or in
parallel even same batteries, please consult with Maxell before
using.
Never expose to open flames.
Exposing to flames could cause the lithium metal to melt, causing
the battery to catch on fire and explode.
Never disassemble the battery.
Do not disassemble the battery, because the separator or gasket could
be damaged, leading to distortion, leakage, overheating, explosion, or
fire.
Never allow liquid leaking from the battery to get in your eyes
or mouth.
Because this liquid could cause serious damage, if it does come in
contact with your eyes, flush them immediately with plenty of water
and consult a physician. Likewise, if the liquid gets in your mouth,
rinse immediately with plenty of water and consult a physician.
Never reverse the positive and negative terminals when
mounting.
Improper mounting of the battery could lead to short-circuiting,
charging or forced-discharging. This could cause distortion,
leakage, overheating, explosion, or fire.
Keep leaking batteries away from fire.
If leakage is suspected or you detect a strong odor, keep the battery
away from fire, because the leaked liquid could catch on fire.
Never short-circuit the battery.
Do not allow the positive and negative terminals to short-circuit.
Never carry or store the battery with metal objects such as a
necklace or a hairpin. Do not take multiple batteries out of the
package and pile or mix them when storing. Otherwise, this could
lead to distortion, leakage, overheating, explosion, or fire.
Never touch the battery electrodes.
Do not allow the battery electrodes to come in contact with your skin
or fingers. Otherwise, the moisture from your skin could cause a
discharge of the battery, which could produce certain chemical
substances causing you to receive a chemical burns.
3
L I T H I U M M A NGA N E SE DIOX I DE BAT T E RY
Warnings — Circuit Design for Back-up Use
Warnings — Disposal
This is a primary battery and cannot be charged. If used in memory
or RTC back-up applications, be sure to use diodes to prevent
charging from the main power source or other batteries, and a
protective resistor to regulate the current as shown in the figure
below. Note that the points described below should be taken into
careful consideration when selecting diodes and protective resistors.
The battery may be
Do not pile up or mix
Tape
regulated by national or batteries.
local regulation.
Please follow the
—
instructions of proper
+
Enlarged view
regulation. As electric
Battery
capacity is left in a
Electric current flows.
discarded battery and
(Example of
it comes into contact
battery insulation)
with other metals, it
These batteries generate heat.
could lead to
distortion, leakage,
overheating, or explosion, so make sure to cover the (+) and (-)
terminals with friction tape or some other insulator before disposal.
Diode
Diode
Load
+5V
Diode
Protective
resistor
Battery
Example (A)
Load
+5V
Diode
Diode
Battery
Example (B)
Caution — Handling/Storage
Supplied voltage to load
Because a diode and a resistor generate the voltage drop on
operating, please take into consideration these voltage drops for
supplied voltage to load.
Never expose the battery to ultrasonic sound.
Exposing the battery to ultrasonic sound may cause short-circuiting
because the inside material is broken into pieces, leading to
distortion, leakage, overheating, explosion, or fire.
Using diodes to prevent charging
Please choose diodes with leak current as small as possible. Please
keep the charged capacity due to leak current to within 1% of
nominal capacity.
Never subject the battery to severe shock.
Dropping, throwing or stomping on the battery may cause distortion,
leakage, overheating, explosion, or fire.
Using and setting protective
resistors
A protective resistor is used to
prevent the battery from being
charged by large surges of current
during diode failure. Please set the
resistor so that the maximum
current shown in the right table is
not exceeded. For example, say a
CR2032 battery is used in sample
circuit (A) in combination with a
main power source 5 volt. Since the
permitted charge current is 10mA
and this battery’s voltage is 3V, let
the resistor be
R>
=(5V-3V)/10mA=0.2k ohm,
meaning that at least 0.2k ohm is
required.
Never short-circuit the battery while installing into equipment.
Please be careful when installing the battery not to short-circuit it with
metal portions of the equipment.
Type
Maximum Current
CR2450HR
15mA
CR2450HR-Ex
15mA
CR2050HR
10mA
CR2032HR
10mA
CR2032H
10mA
CR2032
10mA
CR2025
10mA
CR2016
10mA
CR1632
4.0mA
CR1620
4.0mA
CR1616
2.5mA
CR1220
3.0mA
CR1216
2.5mA
CR17450 AH
20mA
CR17450 A
20mA
CR17335 A
20mA
Use the correct battery suitable for the equipment.
The battery may not be suitable for the specific equipment due to the
using conditions or type of equipment. Please select the suitable
battery according to the handling instructions of the equipment.
Never use or leave the battery in a hot place such as under the direct
rays of the sun or in a car in hot weather.
If you do, this may cause distortion, leakage, overheating, explosion,
or fire.
Never allow the battery to come in contact with water.
If it does, this may cause the battery to rust or lead to distortion,
leakage, overheating, explosion, or fire.
Never store the battery in a hot and humid environment.
Otherwise it may cause battery performance deterioration,
deformation, leakage, overheating, or explosion.
Keep contact force more than 2N.
The battery voltage may be lower than intended value because of
poor contact condition, please keep contact force more than 2N for
suitable contact resistance.
Note: If the diodes broke down, it is necessary for safety to replace
them as soon as possible even though using a protective resistor.
Considering the trouble of diodes and resistors, other safety
measures should be incorporated in the circuit design.
4
C
R
CR
Coin Type Lithium Manganese Dioxide Battery
Overview
The coin type lithium manganese dioxide battery (CR battery) is a small, lightweight battery with an operating voltage of 3V and the ability to
operate over a wide temperature range. It has a wide range of applications, both for powering devices such as wristwatches and electronic
calculators and can be used in all types of electronic devices mainly as memory and RTC backup.
Fig. 1 Relationship between Discharge Current Consumption and Duration Time
Features
Discharge current consumption (µA)
Optimum for Memory and RTC Backup (Fig. 1)
Displays long-term stable operating voltage at low load discharge.
High 3 volt energy density
High energy density. At 3 volts (nominal voltage), it has about twice
the voltage of alkaline button batteries and silver oxide batteries.
Stable discharge characteristics through low internal
resistance and high operating voltage
Employs highly conductive electrolyte, lowering internal resistance
and providing stable operating voltage. This allows stable power to
be obtained, with little change in operating voltage at room
temperature as well as high and low temperatures.
Superior leakage resistance and excellent storage
characteristics (Fig. 2)
Employs a leak-resistant organic electrolyte, giving it better leakage
resistance than battery types using alkaline electrolytes.
Furthermore, the high degree of seal of the seal structure and
application of sealant keep self-discharge to about 1% per year.
Superior high rate discharge characteristics
Construction
Example of Typical Construction
Negative Electrode (Lithium)
Negative Can
Separator
Gasket
(–)
102
101
CR2032H
CR2025
CR2016
CR1616
CR1220
100
10−1
1
2
3
4
5
6
7
8 9 10
Discharge duration time (years)
Fig. 2 Discharge Characteristics after Storage
Voltage (V)
C
R
Primary Battery
3.5
3.3
3.1
2.9
2.7
2.5
2.3
2.1
1.9
1.7
1.5
CR2032H
Discharge load : 15k
Temperature : 20 deg. C
Initial
After stored for 100 days at 60 deg. C
(equivalent to storage at 20 deg. C for 5 years)
0
200
400
600
800
1000
1200
1400
Discharge duration time (hours)
(+)
Positive Electrode
(Manganese Dioxide)
UL Recognized Components
Positive Can
Collector
The coin type lithium manganese dioxide battery is a UL
(Underwriters Laboratories Inc.) recognized component and user
replaceable.
Principle and Reactions
Recognized models:
CR2032H, CR2032, CR2025, CR2016, CR1632, CR1620, CR1616,
CR1220, CR1216
The coin type lithium manganese dioxide battery uses manganese
dioxide (MnO2) as its positive active material, lithium (Li) as its
negative active material, and an organic electrolyte solution.
Certification Number: MH12568
Battery reactions
+
Positive reaction: MnO2Li e– MnOOLi
+
Negative reaction:
Li
Li e–
MnOOLi
Total reaction:
MnO2Li
7
L I T H I U M M A NGA N E SE DIOX I DE BAT T E RY
Applications
Communication Tags
Notebook PCs
OA Machines (Fax, Copiers, Printers)
Electronic Dictionaries
Digital Still Cameras
Camcorders
Medical Instruments, Cash Registers
Keyless Entry Systems
Electronic Meters (Water, Gas, Electricity)
Remote Controllers
FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors)
C
R
Desktop PCs
Calculators
Watches
Portable Game Devices
Products
Model
CR2032H
CR2032
CR2025
CR2016
CR1632
CR1620
CR1616
CR1220
CR1216
3
3
3
3
3
3
3
3
3
Nominal Capacity (mAh)*1
240
220
170
90
140
80
55
36
25
Nominal Discharge
Current (mA)
Operating Temperature
Range (deg. C)*2
0.2
0.2
0.2
0.1
0.1
0.1
0.1
0.1
0.1
Nominal Voltage (V)
Dimensions*3
–20 to +85
Diameter (mm)
20.0
20.0
20.0
20.0
16.0
16.0
16.0
12.5
12.5
Height (mm)
3.2
3.2
2.5
1.6
3.2
2.0
1.6
2.0
1.6
3.0
3.0
2.5
1.7
1.9
1.3
1.1
0.8
0.6
Weight (g)*3
*1
*2
*3
•
Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.
When using these batteries at temperatures outside the range of 0 to +40 deg. C, please consult Maxell in advance for conditions of use.
Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.
Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
Characteristics (CR2032H)
Discharge Characteristics
Temperature Characteristics
Discharge load: 15k
3.5
3.0
3.0
Voltage (V)
Voltage (V)
Temperature: 20 deg. C
3.5
2.5
2.0
1kΩ
1.5
101
3.9kΩ
102
15kΩ
150kΩ 300kΩ 1MΩ
103
104
60 deg. C
20 deg. C
2.5
0 deg. C
2.0
1.5
105
0
Discharge duration time (h)
Pulse Discharge Characteristics
1M continuous
300 5sec.
2.5
1M
2.0
300 5sec.
0
20
40
60
1200
1400
Final voltage: 2.0V
Discharge capacity (mAh)
Voltage (V)
400
600
800
1000
Discharge duration time (h)
250
3.0
1.5
200
Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C
3.5
–10 deg. C
200
–10 deg. C
Discharge capacity (mAh)
8
20 deg. C
150
–20 deg. C
100
50 1
10
80 100 120 140 160 180 200 220 240 260
60 deg. C
102
103
Discharge current (A)
104
CR
External Dimensions with Terminals and Wire Connectors (unit : mm)
CR2032 T6LES
CR2032 T6
CR2032 T23
CR2032 T19
Insulation sleeve
4
3
ø20
4
ø20
ø20
ø20
0.75
5.5
4.5
4.8
20.3
(+)
0.2
20.5
0.75
4
(+)
20.5
0.75
1.8
0.2
4
(–)
(+)
0.2
(–)
16
1.8
(+)
0.2
1.5
4
CR2032 T34
CR2032 T26
CR2032 T33
5
20.5
5.5
5
4.5
(–)
4
4.5
4.5
4
4.5
(–)
1.3
20.5
4.8
4
4.8
4.1
4
4.1
21
4
0.2
18.5
CR2032 WK11
Insulation sleeve
34
70
(+)
7
(+)
3.7
Insulation sleeve
5
(+)
(–)
20.2
ø20
3
1.5
ø20
(–)
Adhesive tape
21
3.7
0.75
4.5
(–)
5
3.5
10.16
1.5
4
10.2
Housing:
Contact:
Wire:
1.5
Actual appearance
Insulation sleeve
34
Insulation sleeve
34
DF13-2S-1.25C (Hirose)
DF13-2630SCF (Hirose)
AWG28 UL1571
CR2032 WK15
CR2032 WK14
CR2032 WK13
CR2032 WK12
Lead wire
12
4
ø20
0.75
1.8
5
(–)
(+)
12
(–)
0.75
(+)
(+)
0.2
7.5
4.2
4
4.5
0.2
(–)
Insulation sleeve
34
Insulation sleeve
22
5
(–)
(–)
Adhesive tape
(–)
(+)
65
Lead wire
12
4.5
(–)
Adhesive tape
(+)
(–)
(+)
4.9
Adhesive tape
60
(+)
(–)
(+)
12
4.5
(+)
(+)
(–)
20.2
(–)
(–)
(+)
(+)
35
(+)
12
4.5
180
20.2
(+)
(–)
20.2
20.2
(+)
(–)
12
C
R
Primary Battery
(–)
Lead wire
Lead wire
12
Lead wire
12
Housing:
Contact:
Wire:
DF13-2S-1.25C (Hirose)
DF13-2630SCF (Hirose)
AWG28 UL1571
Housing:
Contact:
Wire:
Housing:
Contact:
Wire:
DF13-2S-1.25C (Hirose)
DF13-2630SCF (Hirose)
AWG28 UL1571
DF3-4S-2C (Hirose)
DF3-2428SCF (Hirose)
AWG26 UL1007
Housing:
Contact:
Wire:
DF13-2S-1.25C (Hirose)
DF13-2630SCF (Hirose)
AWG28 UL1571
The above are examples. Processing to meet customer requests is possible.
: Horizontal & Through hole Type
: Horizontal & Surface mounting Type
: Vertical & Through hole Type
: Wire connector Type
: Tin plating
Visit our website for more information
http://biz.maxell.com/en/
Go to: Products > Primary Batteries > CR (Coin Type Lithium Manganese Dioxide Battery)
9
Visit our website at: biz.maxell.com
Maxell is accredited with international quality management standard ISO 9001 and international environmental management standard ISO 14001 certifications.
Catalog contents accurate as of January 2018.
Data and dimensions are just reference values.
Contents on this catalog are subject to change without notice.
Committed to the highest quality assurance management standards as well as responsibility to the environment.
Maxell, Ltd. Energy Division
BATTERIES CATALOG(E) MXL-E1801 Printed in Japan